Improving Performance of Dye Sensitized Solar Cells Based On Composite Quasi Solid-State Electrolytes of Poly (ionic liquid) / Ionic liquid / TiO2

A. Benabdellah,K. Negadi, Y. Chaker, B. Fetouhi, M. Debdab, H. Belarbi,M. Hatti

JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS(2021)

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摘要
Composite gel electrolytes of poly(IL) /IL/TiO2 containing poly [1-(hydroxyethyl)-3vinylimidazolium hydrogen sulfate] (poly [EtOHVIM+][HSO4-]) as Poly(IL), 1-butyl-3 methyl-imidazolium hexafluorophosphate ([BMIM] PF6) as IL and Titanium Dioxide (TiO2) are prepared for dye-sensitized solar cells (DSSCs), without any volatile organic solvent. The performance of most (DSSCs) based on TiO2 was limited by the low electron mobility within TiO2. To produce a much higher power conversion efficiency performance and better long-term stability of the composite electrolyte without TiO2, a proper amount of TiO2 was added. Overall power conversion efficiency of 7.46% under simulated AM 1.5 solar spectrum irradiation for (DSSCs) based on the composite electrolytes were showed. This type of composite electrolytes had long-term stability of the (DSSCs), could overcome the drawbacks of volatile liquid electrolytes, and offer a feasible method to fabricate (DSSCs) in future practical applications.
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关键词
poly (IL), Ionic liquid, DSSCs, conversion efficiency, long-term stability
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