N/O co-doped carbon nanocapsule anodes for high rate-performance K-ion batteries

FUNCTIONAL MATERIALS LETTERS(2022)

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摘要
Based on our observations made in our previous work that nitrogen (N)/oxygen (O) dual dopant porous hollow carbon nanocapsules (N/O-CNCs) have state-of-the-art lithium storage and sodium storage capabilities, we further studied their potassium storage performance in this study. It was found that for potassium storage, 259 mA h g(-1) at 0.05 A g(-1) can be retained up to 100 cycles, and 107 mA h g(-1) at 1 A g(-1) can be retained after 100 cycles. Even at 2 A g(-1), an excellent rate capability of 73.4 mA h g(-1) in K-ion batteries (KIBs) was delivered. A capacitive charge-storage mechanism dominated the potassium storage of N/O-CNCs at high rates during the potassiation/depotassiation process through kinetics analysis, ensuring a remarkable rate performance.
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关键词
Carbon materials, N/O co-doped, energy storage and conversion, K-ion batteries, electrical properties
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