Aircraft measurements of water vapor heavy isotope ratios in the marine boundary layer and lower troposphere during ORACLES

This paper presents aircraft in situ measurements of water concentration and heavy water isotope ratios D=H and O-18 =O-16 during the NASA ObseRvations of Aerosols above CLouds and their intEractionS (ORACLES) project. The aircraft measurement system is also presented. The dataset is unique in that (1) it contains both total water and cloud condensed water isotope ratios; (2) it spans sufficient space and time to enable construction of spatially resolved climatology of isotope ratios in the lower troposphere; and (3) it is paired with a wealth of complementary measurements on atmospheric thermodynamic, chemical, aerosol, and radiative properties. Aircraft sampling took place in the southeast Atlantic marine boundary layer and lower troposphere (Equator to 22 degrees S) over the months of September 2016, August 2017, and October 2018. Isotope measurements were made using cavity ring-down spectroscopic analyzers integrated into the Water Isotope System for Precipitation and Entrainment Research (WISPER). From an isotope perspective, the 300 C h of 1 Hz in situ data at levels in the atmosphere ranging from 70m to 7 km represents a remarkably large and vertically resolved dataset. This paper provides a brief overview of the ORACLES mission and describes how water vapor heavy isotope ratios fit within the experimental design. Overviews of the sampling region and sampling strategy are presented, followed by the WISPER system setup and calibration details. The three data formats available to the users are each covered (latitude-altitude curtains, individual vertical profiles, and time series), with illustrative examples to highlight some features of the dataset and provide a plausibility check. The curtains and profiles demonstrate the dataset's potential to provide a comprehensive perspective on moisture transport and isotopic content in this region. Finally, measurement uncertainties are provided. Curtain and vertical profile data for all sampling periods can be accessed at https://doi.org/10.5281/zenodo.5748368 (see Henze et al., 2022). Time series data for the September 2016, August 2017, and October 2018 sampling periods can be accessed at https://doi.org/10.5067/Suborbital/ORACLES/P3/2016_V3, https://doi.org/10.5067/Suborbital/ORACLES/P3/2017_V3, and https://doi.org/10.5067/Suborbital/ORACLES/ P3/2018_V3, respectively (see references for ORACLES Science Team, 2020a-c, 2016 P3 data, 2017 P3 data, and 2018 P3 data).