A Zn(II) coordination polymer assembled by triazole derivative: Crystal structures and energetic behavior

Inorganic Chemistry Communications(2022)

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摘要
A 1D solvent-free energetic coordination polymer [Zn3(μ3-OH)2(att)4]n 1 (Hatt = 4-amino-1,2,4-triazole-5-thiol) was obtained and structurally characterized. Compound 1 displays competitive energetic performance and low mechanical sensitivity, which demonstrates 1 has the potential application in insensitive energetic material.
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关键词
Energetic coordination polymer,Oxygen content,Enthalpy of formation,Mechanical sensitivity,Thermal stability
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