Red-Light-Induced N , N '-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

Savannah M. Stull,Liangyong Mei,Thomas L. Gianetti

SYNLETT（2022）

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摘要

A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N , N '-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obtained in moderate to excellent yields under mild conditions.

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关键词

photoredox catalysis, [3+2] cycloaddition, cyclopropylamines, alkenes, alkynes, dipropyldimethoxyquinacridinium

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