Synthesis and structural characterization of two exotic examples of aryltellurolate cluster compounds: [Ag4Hg(µ-TeoPy-κTe)3(µ3-TeoPy-κTe)2(µ3-TeoPy-κN,Te)(PPh3)2] and [{Cu(phen)}3(µ3-TePh)3(CuCl)]⋅0.5C2H6O

Felipe D. da Silva,Bruno N. Cabral,Artur L. Hennemann,Nahum R. Pineda,Robert A. Burrow,Paulo C. Piquini,Ernesto S. Lang,Sailer S. dos Santos

Inorganic Chemistry Communications（2021）

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摘要

•New aryltellurolate based clusters presented exotic molecular structures.•Topological parameters and ELF maps were employed to evaluate the chemical bonds.

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关键词

Ternary cluster,CuI-TeII and AgI-HgII-TeII clusters,Bis(phenyl)ditellane,Bis(2-pyridyl)ditellane

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