Ferralactone formation from iron acetylides and carbon dioxide

Journal of Organometallic Chemistry(2022)

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摘要
•Formation of ferralactones by reaction of iron hydrido acetylide complexes with carbon dioxide.•Spectroscopic characterization of unstable side-on-bound acetylene and phenylacetylene complexes.•Reaction of side-on-bound phenylacetylene complexes with carbon dioxide affords a different isomer of ferralactone where the phenyl ring is attached the metal-bound carbon of the metalalactone ring.
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关键词
Carbon dioxide,Ferralactone,Metalalactone,Iron acetylide,Metal acetylide
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