Iron-Catalyzed Epoxidation of Linear alpha-Olefins with Hydrogen Peroxide

CHEMCATCHEM(2022)

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摘要
The combination of Fe(OTf)(2) with N-methyl bis(picolylamine) (Me-bpa) L7 enables epoxidation of linear olefins including terminal, internal, and cyclic ones, using hydrogen peroxide as terminal oxidant under mild conditions. In the presence of picolinic acid as additive improved yields of epoxides up to 75 % have been achieved.
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关键词
iron, epoxidation, olefin, hydrogen peroxide, picolinic acid
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