Structural speciation in chemical reactivity profiling of binary-ternary systems of Ni(II) with iminodialcohol and aromatic chelators

Systematic synthetic reactivity in binary-ternary Ni(II):iminodipropanol:N,N’-aromatic chelator systems unravels an interwoven network of hybrid mononuclear Ni(II) complexes with variable coordination sphere composition. Structural variant and interconversion transformations exemplify distinct physicochemical properties, revealing diverse lattice architecture-spectroscopic correlations with theoretical electronic modeling and formulating nickel chemical reactivity profiles-patterns useful in materials development.