Improved singlet oxygen generation in rhenium(I) complexes functionalized with a pyridinyl selenoether ligand

Karina P. Morelli Frin, Leonardo Henrique de Macedo, Samuel Santos de Oliveira,Rodrigo L.O.R. Cunha,Jesus Calvo-Castro

Polyhedron（2022）

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摘要

•Three novel fac-[Re(CO)3(NN)(4-(phenylseleno)-pyridine)]+ complexes.•Optoelectronic properties critically influenced by organoselenide ligand.•Improved singlet oxygen generation over reported structural analogues.

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关键词

Rhenium(I) compounds,Organoselenide ligand,3MLCT emission,Singlet oxygen,Photosensitizers

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