Linear Assembly of Two-Patch Silica Nanoparticles and Control of Chain Length by Coassembly with Colloidal Chain Stoppers

The self-assembly of patchy nanosized building blocks is an efficient strategy for producing highly organized materials. Herein we report the chaining of divalent silica nanoparticles with polystyrene patches dispersed in tetrahydrofuran triggered by lowering the solvent quality. We study the influence of the patch-to-particle size ratio and show that the nature of the added nonsolvent, for example, ethanol, water, or salty water, and its volume fraction should be carefully adjusted. We demonstrate that colloidal assembly initially obeys the kinetic model of step-growth polymerization and that beyond a certain length, the chains have the possibility to cyclize. We also show that the length of the chains can be controlled by the addition of one-patch silica nanoparticles, which act as colloidal analogues of chain stoppers.