Redox-Neutral Ni-Catalyzed sp3C-H Alkylation of alpha-Olefins withUnactivated Alkyl Bromides br

Mikkel B. Buendia,Bradley Higginson,Soren Kegnaes,Soren Kramer,Ruben Martin

ACS Catalysis（2022）

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摘要

A light-induced redox-neutral Ni-catalyzed sp3C-H alkylation of unactivated alkenes with alkyl bromides possessing beta-hydrogens is described herein. The method is distinguished by itssimplicity, wide scope, and exquisite regio- and chemoselectivityprofile, thus offering an entry point to forge sp3-sp3architectures.

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关键词

nickel, photochemistry, cross-coupling, alkylation, olefin functionalization

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