Helical Anthracene-Ethyne-Based MOF-74 Analogue

Patricia Scheurle,Andre Maehringer, Tabea Haug,Alexander Biewald, Daniel Axthammer,Achim Hartschuh,Lena Harms,Gunther Wittstock,Dana D. Medina,Thomas Bein

CRYSTAL GROWTH & DESIGN（2022）

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摘要

A flexible, electro n-rich building block was integrated into the backbone of a metal-organic framework with a MOF-74 topology. The building block comprises a central anthracene core connected to acetylene groups. Solvothermal synthesis with Mn2+ yields a highly crystalline anthracene-ethyne-based MOF-74 structure. It shows an unusual helical rod-like morphology, exhibiting visible light absorption and photo-luminescence.

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