Nitro group as a redox switch in urea-based receptors of anions

Journal of Electroanalytical Chemistry(2021)

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摘要
•NO2 group was used as an electrochemical binding/release switch in anion receptors.•Binding enhancement factor of the receptor is dependent on NO2 position.•Reduction processes were elucidated by electrochemical/spectroelectrochemical methods.•Complexation of dihydrogen phosphate changes the receptor reduction mechanism.
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关键词
host-guest systems,redox switch,electrochemistry,urea-based receptors,spectroelectrochemistry
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