Synthesis of α‑Aminosilanes by 1,2-Metalate Rearrangement Deoxygenative Silylation of Aromatic Amides

An efficient nickel-catalyzed deoxygenative silylation reaction of aromatic amides with silylboranes in the presence of a Sm/SmI2 system for the construction of α-aminosilanes is described. This strategy provides a direct method for synthesizing α-aminosilanes with high efficiency and good functional group compatibility and includes readily accessible starting materials and valuable products.