A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

Jiaxin Tian,Marie Cordier,Christophe Bour,Audrey Auffrant,Vincent Gandon

Chemical Communications（2022）

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摘要

The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(i) salt. DFT study of this compound reveals the low valent character of the N(i) center.

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