Assessment and Implication of PAHs and Compound-Specific delta C-13 Compositions in a Dated Marine Sediment Core from Daya Bay, China

PAHs in a sediment core covering similar to 120 years from Daya Bay in South China Sea were extracted using Soxhlet and high performance thin layer chromatography, and the compound-specific delta C-13 were analyzed using gas chromatography-combustion-isotopic ratio mass spectrometry. The concentrations of PAHs ranged from 99.3 to 676 ng g(-1), with high molecular weight PAHs as a key component. PAHs' compound-specific delta C-13 ranged from -35.02 parts per thousand to -16.14 parts per thousand. The patterns of 16 PAHs, molecular ratios, and compound specific delta C-13 compositions indicate important pyrolytic and petrogenic sources: PAHs derived predominantly from pyrogenic sources (including coal and wood incomplete combustion) before the 1960s, while after the 1960s, they derived predominantly from mixed pyrogenic and petrogenic sources (including automotive exhaust emissions, oil spills, and coal and wood incomplete combustion). Our results can provide important insights into organic pollution emissions influenced by human activities and the urbanization of Daya Bay.