Post-synthetic ligand cyclization in metal–organic frameworks through functional group connection with regioisomerism

Dasom Kim,Haneul Yoo,Kyunghwan Kim,Dongwook Kim,Ki Tae Kim,Cheoljae Kim,Jin Yeong Kim,Hoi Ri Moon,Min Kim

Chemical Communications（2022）

引用 8|浏览2

暂无评分

摘要

A covalent connection between two orthogonal functional groups (–NH2 and –OH) in metal–organic frameworks (MOFs) has been developed. This post-synthetic ligand cyclization (PSLC) was successfully demonstrated to synthesize a benzoxazole-functionalized MOF from a Zr-based UiO-66–2,3-(NH2)(OH) under microwave irradiation. In contrast, the regioisomeric UiO-66–2,5-(NH2)(OH) only produces a non-cyclized formamide-functionalized MOF.

查看译文

关键词

ligand,metal–organic frameworks,regioisomerism,functional group connection,post-synthetic

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要