Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline

Alexey A. Nikolin,Alexander A. Korlyukov,Eugenia P. Kramarova, Alexandr R. Romanenko,Dmitry E. Arkhipov, Dmitry V. Tarasenko,Sergey Yu. Bylikin,Yuri I. Baukov,Vadim V. Negrebetsky

Mendeleev Communications（2022）

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摘要

A novel organosilicon complex of N-acetylvaline was synthesized by the reaction of the relative disiloxane derivative with BF3 etherate. According to X-ray and NMR data, the silicon atom of the final product is pentacoordinated in both the solid state and solution. The coordination state of silicon was correctly predicted by quantum-chemical calculations.

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organosilicon compounds, amino acids, valine, fluorosilanes, synthesis, pentacoordinate silicon, X-ray diffraction study, quantum-chemical analysis

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Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline

Synthesis and structure of (O → Si)-chelate fluorosilane, a novel complex of pentacoordinate silicon with N-acetylvaline