Electrochemistry of icosahedral metal full and half sandwich metallacarboranes in phosphate buffers

Journal of Electroanalytical Chemistry(2022)

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摘要
•Electrochemistry of sandwich (Cr, Fe Co, Ni) metallacarbores in aqueous solution.•The electrochemical process connected with metal atom is reversible.•Electrochemical processes connected with the boron cage are irreversible.
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关键词
Glassy carbon electrode,Dicarbollides,Molecular sensors and probes
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