The role of defects in the photoconversion of 2-propanol on rutile titania: Operando spectroscopy combined with elementary studies

Journal of Catalysis(2022)

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摘要
•In situ study of photoconversion of 2-propanol on TiO2(110) in UHV and liquid phase.•Thermal and photochemical reaction pathways forming propane, propene & acetone.•Increased activity in presence of defects and oxygen; water blocking active sites.
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关键词
Rutile TiO2(110),Photo Oxidation,Acetone,Isopropanol,UV Irradiation,UHV,Liquid Phase,PC-IRRAS,Model Catalysis
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