Hydrothermal systems with radiogenic Sr in the North Qaidam ultrahigh-pressure metamorphic belt, NE Tibetan Plateau and implications for regional dissolved Sr budget

Hydrothermal systems, including hot springs and hydrothermal calcite, are common features of orogenic belts. The hot springs and hydrothermal calcite in the Himalayas are characterized by radiogenic Sr related to metamorphic processes. Such metamorphism-driven processes have contributed significant amounts of radiogenic Sr to rivers and groundwater, which has affected the evolution of global seawater 87Sr/86Sr during the Cenozoic. However, whether such hydrothermal systems with highly radiogenic Sr occur in other continental collisional belts with intense metamorphism remains unknown, which hinders a better understanding of regional and global Sr cycles. Compiled 87Sr/86Sr ratios in surface water around the Tibetan Plateau show that the Qilian-North Qaidam region displays a higher 87Sr/86Sr ratio than other regions, except for the Himalayas. Here, we report 87Sr/86Sr ratios of a hydrothermal system on the northern margin of the early Paleozoic North Qaidam ultrahigh-pressure metamorphic belt, NE Tibetan Plateau. The high 87Sr/86Sr ratios (0.757–0.734) of the hot spring water and the acetic acid leachates of the surrounding rocks (gneiss and schist) with other isotopic tracers (e.g., oxygen, hydrogen, lithium, and boron isotopes) indicate that 1) Sr was exchanged during metamorphism between carbonate and silicate phases in crustal rocks and the high 87Sr/86Sr ratio of the hot spring water was acquired from a deep water-rock reaction process; and 2) hydrothermal systems around the Qilian-North Qaidam region operate like those in the Himalayas. Mass balance calculations indicate that the metamorphism-forced hydrothermal system plays a key role in delivering radiogenic Sr to rivers and lakes and yielding higher 87Sr/86Sr ratios in surface water around the Qilian Shan region than in the surrounding areas. The reactivated early Paleozoic Qilian orogenic belts with ultrahigh-pressure metamorphism caused by the India-Asia collision have significantly impacted the regional water 87Sr/86Sr ratio, suggesting that the reactivated old orogenic belts with intense metamorphic processes formed by continental subduction/collision can play a pivotal role in regulating past seawater 87Sr/86Sr evolution.