(Acetylacetonato-κ2O,O′)bis[2-(5-methyl-3-phenylpyrazin-2-yl-κN1)phenyl-κC1]iridium(III)
Acta Crystallographica Section E-structure Reports Online(2012)
摘要
In the title complex, [Ir(C17H13N2)2(C5H7O2)], the IrIII atom is hexacoordinated in a distorted octahedral geometry by two C,N-bidentate 2-(5-methyl-3-phenylpyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetylacetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other.
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关键词
acetylacetonato-κ<sup>2</sup><i>o</i><i>o</i>′bis2-5-methyl-3-phenylpyrazin-2-yl-κ<i>n</i><sup>1</sup>phenyl-κ<i>c</i><sup>1</sup>iridiumiii
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