A Transaminative Synthesis of 9-Amino-9-fluorenecarboxylic Acid Esters.
ChemInform(2010)
摘要
Abstract The benzyl imines of several fluorenones were treated with base, followed by methyl chloroformate, to introduce the carbomethoxy group at the 9-fluorenyl position. Imine hydrolysis afforded the title compounds. The reaction was readily conducted on a 30-g scale.
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