Crystalline and Glassy Phases in the Ternary System Tl/Bi/Cl: Synthesis and Crystal Structures of the Thallium(I) Chloridobismutates(III) Tl3BiCl6 and TlBi2Cl7.
ChemInform（2010）
摘要
Tl3BiCl6 (I) is prepared by heating a mixture of TlCl and BiCl3 in a molar ratio of 3:1 to 480 °C for 10 h followed by slow cooling.
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