Low Temperature n-Butyllithium-Induced [3,3]-Sigmatropic Rearrangement/Electrophile Trapping Reactions of Allyl-1,1-dichlorovinyl Ethers. Synthesis of β-, γ- and δ-Lactones.

ChemInform(2014)

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摘要
The BuLi-mediated [3,3]-sigmatropic rearrangement of allyl-1,1-dichlorovinyl ethers (I) and (XII) and subsequent quenching with ketones afford desired β-lactones (III), (V), and (XIII) in moderate to high yields.
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