Synthesis of Enantiomerically Enriched Indolines and Tetrahydroisoquinolines from (S)‐Amino Acid‐Derived Chiral Carbocations: An Easy Access to (3S,4R)‐Demethoxy‐3‐isopropyl Diclofensine.
ChemInform(2015)
摘要
The intramolecular Friedel—Crafts-type reaction is promoted by a Lewis acid and exhibits high trans-diastereoselectivity.
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关键词
Tetrahydroisoquinoline,Chiral Catalysts
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