A Convenient Synthesis of New Biological Active 5‐Imino‐4‐thioxo‐2‐imidazolidinones Involving Acetonitrile Electrogenerated Base.

Najwa Sbei,Belen Batanero,Fructuoso Barba,Beya Haouas,L. Fuentes,Mohamed Lamine Benkhoud

ChemInform（2016）

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摘要

Acetonitrile is electrolyzed to form cyanomethyl anion, which not only deprotonizes benzyl amines [e.g. (I)] to give a nitride intermediate, but also forms an organomagnesium compound with the magnesium anode.

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Microwave-Assisted Synthesis

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