Mesogenic coordination polymers based on Ru2(II,II)‐paddle‐wheel units exhibit high electrical conductivity

Leonardo Rossi,Cristián Huck-Iriart,Lisandro Giovanetti,Paula Soledad Antonel,Ernesto Marceca,Fabio Daniel Cukiernik

European Journal of Inorganic Chemistry（2021）

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摘要

Coordination polymers based on diruthenium units axially linked by tetrazine self-organize in columnar mesophases from which oriented fiber have been extruded. High electrical conductivity has been measured along these fibers, showing such coordination polymers behave as molecular wires.

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关键词

Coordination polymers, Diruthenium carboxylates, Electrical conductivity, Extruded fibers, Metallomesogens

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