Radical Mechanism of IrIII/NiII-Metallaphotoredox-Catalyzed C(sp3)–H Functionalization Triggered by Proton-Coupled Electron Transfer: Theoretical Insight

Yu-Jiao Dong,Bo Zhu,Yun Geng,Zhi-Wen Zhao,Zhong-Min Su,Wei Guan

CCS Chemistry（2021）

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摘要

Photoredox catalysis can be induced to activate organic substrates or to modulate the oxidation state of transition-metal catalysts via unique single-electron transfer processes, so as to achieve c...

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关键词

C(sp(3))-H functionalization, photoredox catalysis, iridium, nickel, density functional calculations

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