CO activation by the heterobinuclear transition metal-iron clusters: A photoelectron spectroscopic and theoretical study

Jumei Zhang,Zhiling Liu,Gang Li,Hongjun Fan,Ling Jiang,Hua Xie

Journal of Energy Chemistry（2021）

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摘要

Photoelectron spectroscopic and theoretical studies reveal the CO activation by the heterobinuclear M–Fe (M = Ti, V, Cr) clusters via the formation of a metal-Fe bonded M–Fe(CO)4 structure.

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关键词

CO activation,Metal carbonyl,Alloy surface,Photoelectron velocity-map imaging spectroscopy

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