Programmed Molecular Construction: Driving the Self-Assembly by Coordination and Hydrogen Bonds Using 6‑(Pyridin-2-yl)-1,3,5-triazine-2,4-diamine with M(NO3)2 Salts

A new series of hydrogen-bonded metallotecton networks 6–9 of the general formula [M(2)2(NO3)2] were obtained from the reaction of 6-pyridin-2-yl-[1,3,5]-triazine-2,4-diamine 2 with transition-metal ions [M: Co(II), Ni(II), Cu(II), and Zn(II)]. Their supramolecular networks and associated properties were characterized by single-crystal and powder X-ray diffraction, IR, solid-state UV–vis spectroscopy, and thermogravimetric analysis associated with differential scanning calorimetry. On the basis of standard patterns of coordination involving 2,2′-bipyridine and simple derivatives, compound 2 binds transition-metal ions with predictable constitution and the diaminotriazinyl (DAT) groups serve orthogonally to ensure the intermetallotecton interactions by hydrogen bonding according to well-established motifs I–III. As expected, compound 2 formed octahedral 2:1 metallotectons with M(NO3)2, and further self-assembled by hydrogen bonding of the DAT groups to produce pure, crystalline, homogeneous, and thermally ...