The AlAl triple bond in Al₂X₅⁺ and Al₂X₆²⁺ (X = Li, Na) clusters with multiple alkali metal coordination

Yingying Liu,Changyan Zhu,Chaoxia Wen,Min Zhang,Yun Geng,Xingman Liu,Zhongmin Su

New Journal of Chemistry（2020）

引用 4|浏览2

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摘要

The AlAl triple bond does not change obviously with the increase in the number of Li+ or Na+ and [AlAl]4− is the core to stabilize these clusters and its stability is hard to be affected by the numbers and positions of the Li+ or Na+.

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The AlAl triple bond in Al2X5+ and Al2X62+ (X = Li, Na) clusters with multiple alkali metal coordination

The AlAl triple bond in Al₂X₅⁺ and Al₂X₆²⁺ (X = Li, Na) clusters with multiple alkali metal coordination