Synthesis of macrocyclic poly(α-hydroxyl acids) via DABCO-mediated ROP of O-carboxylanhydrides derived from l-phenylalanine even in the presence of an alcohol

Jinpeng Liang,Ting Yin,Song Han,Jing Yang

Polymer Chemistry（2020）

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摘要

On exploration of a catalytic system including simple 1,4-diazabicyclo-[2.2.2]octane (DABCO), triethylboron (TEB) and benzylalcohol (BnOH), a new pathway to achieve cyclic PAHAs was developed via ROP of OCAs.

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