Semi-conducting mixed-valent X₄TCNQ^I−/II− (X = H, F) charge-transfer complexes with C₆H₂(NH₂)₄

Ashley L. Sutton,Brendan F. Abrahams,Deanna M. D’Alessandro,Lars Goerigk,Timothy A. Hudson,Richard Robson,Pavel M. Usov

Journal of Materials Chemistry C（2020）

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摘要

A pair of semi-conducting, charge transfer complexes of composition, [C6H2(NH2)4][TCNQ] and [C6H2(NH2)4][F4TCNQ] is described in which the TCNQ and F4TCNQ species each exhibit a -I/-II mixed-valent state.

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Semi-conducting mixed-valent X4TCNQI−/II− (X = H, F) charge-transfer complexes with C6H2(NH2)4

Semi-conducting mixed-valent X₄TCNQ^I−/II− (X = H, F) charge-transfer complexes with C₆H₂(NH₂)₄