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Dynamic dimer–monomer equilibrium in a cycloruthenated complex of [Re(η6-C6H6)2]+

Daniel Hernández-Valdés,Lionel Wettstein,Ricardo Fernández-Terán,Benjamin Probst,Thomas Fox,Bernhard Spingler,Qaisar Nadeem,Roger Alberto

Chemical Communications（2020）

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摘要
Cycloruthenation of a rhenium-sandwich derivative gives a hetero-bimetallic Re/Ru complex with planar chirality, which reversibly dimerizes to the meso-form of the individual complexes.
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