Remote azidation of C(sp³)–H bonds to synthesize δ-azido sulfonamidesviairon-catalyzed radical relay

Organic & Biomolecular Chemistry（2020）

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摘要

A selective remote C–H azidation was developed with an iron catalyst playing dual roles as a radical initiator and terminator.

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Remote azidation of C(sp3)–H bonds to synthesize δ-azido sulfonamidesviairon-catalyzed radical relay