Octahedral copper(ii)-diimine complexes of triethylenetetramine: effect of stereochemical fluxionality and ligand hydrophobicity on Cu^II/Cu^Iredox, DNA binding and cleavage, cytotoxicity and apoptosis-inducing ability

Mitu Sharma,Mani Ganeshpandian,Munmi Majumder,Ajaykamal Tamilarasan,Mukesh Sharma,Rupak Mukhopadhyay,Nashreen S. Islam,Mallayan Palaniandavar

Dalton Transactions（2020）

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摘要

Stereochemical fluxionality of octahedral [Cu(trien)(diimine)]2+complexes determines the CuII/CuIredox potential, DNA binding affinity, ROS generation, cytotoxicity and apoptosis-inducing ability.

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Octahedral copper(ii)-diimine complexes of triethylenetetramine: effect of stereochemical fluxionality and ligand hydrophobicity on CuII/CuIredox, DNA binding and cleavage, cytotoxicity and apoptosis-inducing ability

Octahedral copper(ii)-diimine complexes of triethylenetetramine: effect of stereochemical fluxionality and ligand hydrophobicity on Cu^II/Cu^Iredox, DNA binding and cleavage, cytotoxicity and apoptosis-inducing ability