Rationally assembled nonanuclear lanthanide clusters: Dy₉ displays slow relaxation of magnetization and Tb₉ serves as luminescent sensor for Fe³⁺, CrO₄²⁻ and Cr₂O₇²⁻

Yuan Huang,Yaru Qin,Yu Ge,Yanfeng Cui,Xiamei Zhang,Yahong Li,Jinlei Yao

New Journal of Chemistry（2019）

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摘要

The utilization of a Schiff base ligand 2-((2-hydroxy-4-methoxy-benzylideneamino)methyl)phenol (H2L) afforded five nonanuclear lanthanide(iii) clusters. Dy9 displays slow relaxation of magnetization and Tb9 serves as luminescent sensor for Fe3+, CrO42− and Cr2O72−.

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Rationally assembled nonanuclear lanthanide clusters: Dy9 displays slow relaxation of magnetization and Tb9 serves as luminescent sensor for Fe3+, CrO42− and Cr2O72−

Rationally assembled nonanuclear lanthanide clusters: Dy₉ displays slow relaxation of magnetization and Tb₉ serves as luminescent sensor for Fe³⁺, CrO₄²⁻ and Cr₂O₇²⁻