Polymorphs, phase transitions and stability in BaM₂(PO₄)₂ M = Mn, Fe, Co systems

Bastien Leclercq,Houria Kabbour,Angel Arevalo-Lopez,Marielle Huvé,Sylvie Daviero-Minaud,Claire Minaud, Ignacio Blazquez Alcover,Olivier Mentré

Inorganic Chemistry Frontiers（2020）

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摘要

Here we show the complexity in the BaM2(PO4)2 (M = Mn, Fe, Co) phase diagram. The original structures are discussed in terms of structural stability by comparison between the systems and by analogy to the number of transitions in these phase diagrams.

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Polymorphs, phase transitions and stability in BaM2(PO4)2 M = Mn, Fe, Co systems

Polymorphs, phase transitions and stability in BaM₂(PO₄)₂ M = Mn, Fe, Co systems