A Pd₃L₆ supramolecular cage incorporating photoactive [2.2]paracyclophane units

Diego Rota Martir,Lucie Delforce,David B. Cordes,Alexandra M. Z. Slawin,Stuart L. Warriner,Denis Jacquemin,Eli Zysman-Colman

Inorganic Chemistry Frontiers（2020）

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摘要

In this work we report two photoactive [2.2]paracyclophane (pCp) ligands and a luminescent Pd3L6 cage incorporating these ligands, which exhibits blue emission both in solution and in the powder state.

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A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane units

A Pd₃L₆ supramolecular cage incorporating photoactive [2.2]paracyclophane units