Observation of counterion effects and dimensionality reduction in single-crystal (EDO-TTF)₂SbF₆ with ultrafast electron diffraction

Lai Chung Liu,Yifeng Jiang,Henrike M. Mueller-Werkmeister,Cheng Lu,Gustavo Moriena,Manabu Ishikawa,Yoshiaki Nakano,Hideki Yamochi,R. J. Dwayne Miller

EPJ Web of Conferences（2019）

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摘要

Femtosecond electron diffraction is used to resolve structural dynamics in single-crystal (EDO-TTF)2XF6 (X = P, Sb). The retarded and lower-dimensional dynamics of the latter illustrate the dominant role of counterion motion in stabilizing electron transfer.

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Observation of counterion effects and dimensionality reduction in single-crystal (EDO-TTF)2SbF6 with ultrafast electron diffraction

Observation of counterion effects and dimensionality reduction in single-crystal (EDO-TTF)₂SbF₆ with ultrafast electron diffraction