Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]−via reaction with CS2
Dalton Transactions(2019)
摘要
Hydride-insertion reactivity of DNIC [(NO)2Fe(η2-BH4)]− promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)]− featuring Fe 3dz2-to-HCS2 π* backbonding interaction.
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