A series of Ln₄^III clusters: Dy₄ single molecule magnet and Tb₄ multi-responsive luminescent sensor for Fe³⁺, CrO₄²⁻/Cr₂O₇²⁻ and 4-nitroaniline

Yaru Qin,Yu Ge,Shasha Zhang,Hao Sun,Yu Jing,Yahong Li,Wei Liu

RSC Advances（2018）

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摘要

Five tetranuclear lanthanide clusters were synthesized. Dy4 complex exhibits single molecule magnet (SMM) behavior and Tb4 compound shows sensing properties towards Fe3+, CrO42−, Cr2O72− and 4-nitroaniline (4-NA).

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A series of Ln4III clusters: Dy4 single molecule magnet and Tb4 multi-responsive luminescent sensor for Fe3+, CrO42−/Cr2O72− and 4-nitroaniline

A series of Ln₄^III clusters: Dy₄ single molecule magnet and Tb₄ multi-responsive luminescent sensor for Fe³⁺, CrO₄²⁻/Cr₂O₇²⁻ and 4-nitroaniline