Nucleophile and base differentiation of pyridine with tetrahalocatechols and the formation of manganese(iii)-catecholate and pyridinium-catecholate complexes for the in situ generation of H₂O₂ from O₂

Nicholas Bakewell,Rumintha Thavarajah,Majid Motevalli,Tippu S. Sheriff

New Journal of Chemistry（2017）

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摘要

The structures of two novel pyridinium catecholates are reported by reaction of pyridine with tetrachloro-o-benzoquinone and tetrabromocatechol; with tetrachlorocatechol pyridine acts as a base with the structure of the pyridinium-catecholate salt reported.

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Nucleophile and base differentiation of pyridine with tetrahalocatechols and the formation of manganese(iii)-catecholate and pyridinium-catecholate complexes for the in situ generation of H2O2 from O2

Nucleophile and base differentiation of pyridine with tetrahalocatechols and the formation of manganese(iii)-catecholate and pyridinium-catecholate complexes for the in situ generation of H₂O₂ from O₂