Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C₂ Symmetric Digold Catalysts

Cristina García-Morales,Beatrice Ranieri,Imma Escofet,Laura López-Suarez,Carla Obradors,Andrey I. Konovalov,Antonio M. Echavarren

Journal of the American Chemical Society（2017）

引用 86|浏览0

暂无评分

摘要

The enantioselective intermolecular gold(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A.

查看译文

关键词

cyclobutenes,synthesis,cycloaddition,catalysts,intermolecular

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要

Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C2 Symmetric Digold Catalysts

Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C₂ Symmetric Digold Catalysts