Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 − x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system

Chemical Communications（2016）

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摘要

These bimetallic MOFs contain [Cu(pyz)2]2+ sheets and MF6n− octahedra whereby only the Cu(ii) moments magnetically order.

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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system