Efficient electro/photocatalytic water reduction using a [Ni^II(N₂Py₃)]²⁺ complex

Pavithra H. A. Kankanamalage,Shivnath Mazumder, Vishwas Tiwari,Kenneth K. Kpogo,H. Bernhard Schlegel,Cláudio N. Verani

Chemical Communications（2016）

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摘要

A nickel-based electro/photocatalyst acts efficiently toward water reduction with a remarkable TON of 3500. Involvement of the ligand-reduced [NiIL˙] species is proposed.

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Efficient electro/photocatalytic water reduction using a [NiII(N2Py3)]2+ complex

Efficient electro/photocatalytic water reduction using a [Ni^II(N₂Py₃)]²⁺ complex