Asymmetric organocatalytic Michael addition of cyclopentane-1,2-dione to alkylidene oxindole

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY(2022)

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摘要
An asymmetric Michael reaction between cyclopentane-1,2-dione and alkylidene oxindole was studied in the presence of a multifunctional squaramide catalyst. Michael adducts were obtained in high enantioselectivities and in moderate diastereoselectivities.
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关键词
cyclopentane-1, 2-dione, enantioselective catalysis, Michael addition, organocatalysis, squaramide
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