Cascade aryne insertion/vinylogous aldol reaction of vinyl-substituted β-keto/enol carbonyls

Nandikolla Krishna Chaitanya,Y N Sambasiva Rao,Venkata Surya Kumar Choutipalli,Prathama S Mainkar,Venkatesan Subramanian,Srivari Chandrasekhar

Chemical Communications（2022）

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摘要

Cyclic and acyclic vinyl substituted β-keto/enol carbonyl substrates, on reaction with arynes, result in differentially substituted naphthyl carbocycles, hitherto difficult to synthesize with existing protocols. While the substitutions on the arynes have no role, the ring size of the cyclic β-keto/enol esters has a profound influence on the product formation.

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